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Synthesis, Characterization and Reactivity of Ylidyne and -Ylido Complexes Supported by Scorpionato

Author: Priyabrata Ghana

Publishing date: 2019

This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry of compounds featuring triple bonds of the heavier Group-14 elements Si-Pb with transition metals is a very challenging research area, which combines modern molecular main-group element with transition-metal chemistry, and is of fundamental importance for the understanding of chemical bonding. During the last 15 years, the research in this area has witnessed considerable progress in isolating a series of closed-shell tetrylidyne complexes. However, despite numerous attempts,

590.00 zł

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Synthesis, Characterization and Reactivity of Ylidyne and -Ylido Complexes Supported by Scorpionato